MSDS OF BITUMEN MASTIC

SAFETY DATA SHEET BITUMEN MASTIC

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name   BITUMEN MASTIC 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Supplier ATDM CO.LTD [email protected] 1.4. Emergency telephone number(24 Hours)

SECTION 2: HAZARDS IDENTIFICATION OF BITUMEN MASTIC

2.1. Classification of the substance or mixture Classification (1999/45/EEC)        Carc. Cat. 3;R40. N;R51/53. R10. 2.2. Label elements Contains              FUEL, DIESEL NO 2; GASOIL – UNSPECIFIED Labelling Risk Phrases Safety Phrases 2.3. Other hazards Harmful Dangerous for the environment R10         Flammable. R40         Limited evidence of a carcinogenic effect. R51/53  Toxic to aquatic organisms,  may cause long-term adverse effects in the aquatic environment. S2           Keep out of the reach of children. S13         Keep away from food,  drink and animal feeding stuffs. S29/56  Do not empty into drains,  dispose of this material and its container at hazardous or special waste collection point. S36/37/39            Wear suitable protective clothing,  gloves and eye/face protection. S46         If swallowed,  seek medical advice immediately and show this container or label. S51         Use only in well-ventilated areas. S61         Avoid release to the environment. Refer to special instructions/safety data sheets. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures
FUEL, DIESEL NO 2; GASOIL – UNSPECIFIED           1-5% CAS-No.: 68476-34-6            EC No.: 270-676-1
Classification (EC 1272/2008)       Classification (67/548/EEC) EUH066                Xn;R65. Carc. 2 – H351     Carc. Cat. 3;R40. Asp. Tox. 1 – H304            N;R51/53. Aquatic Chronic 2 – H411               R66.
ISODECYLOXYPROPYLAMINE ACETATE                   < 1% CAS-No.: 28701-67-9            EC No.: 249-166-8
Classification (EC 1272/2008)       Classification (67/548/EEC) Acute Tox. 4 – H302         Xn;R22. Skin Corr. 1B – H314         C;R34. Aquatic Acute 1 – H400   N;R50/53. Aquatic Chronic 1 – H410
NAPHTHA (PETROLEUM), HYDROSULFURIZED HEAVY; LOW BOILING*     5-10% CAS-No.: 64742-82-1         EC No.: 265-185-4
Classification (EC 1272/2008)       Classification (67/548/EEC) Flam. Liq. 3 – H226            Xn;R65. EUH066                N;R51/53. STOT SE 3 – H336               R10,R66,R67. Asp. Tox. 1 – H304 Aquatic Chronic 2 – H411
PHOSPHORIC ACID …%                                 < 1% CAS-No.: 7664-38-2              EC No.: 231-633-2
Classification (EC 1272/2008)       Classification (67/548/EEC) Skin Corr. 1B – H314         C;R34
PROPAN-2-OL                                   < 1% CAS-No.: 67-63-0   EC No.: 200-661-7             Registration Number: 01-2119457558-25
Classification (EC 1272/2008)       Classification (67/548/EEC) Flam. Liq. 2 – H225            F;R11 Eye Irrit. 2 – H319              Xi;R36 STOT SE 3 – H336               R67
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Composition Comments Product contains silica which in the form the product is supplied is not hazardous,  however inhalation of  dust generated from dried material must be avoided. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Remove victim immediately from source of exposure.  Move the exposed person to fresh air at once.  Get medical attention. Ingestion DO NOT induce vomiting. Get medical attention immediately. Skin contact Promptly flush contaminated skin with soap or mild detergent and water.  Promptly remove clothing if penetrated and flush the skin with water.  Get medical attention promptly if symptoms occur after washing. Eye contact Rinse the eye with water immediately.  Continue to rinse for at least 15 minutes and get medical attention. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Use fire-extinguishing media appropriate for surrounding materials. 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protective equipment for fire-fighters Wear self contained breathing apparatus SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact. Ensure adequate ventilation. Wear personal protective equipment. Wear self contained breathing apparatus. 6.2. Environmental precautions Prevent entry into drains and water courses. 6.3. Methods and material for containment and cleaning up Pick up with vacuum or absorbent solid,  store in closed container for disposal. 6.4. Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid spilling,  skin and eye contact.  Ventilate well,  avoid breathing vapours. Use approved respirator if air contamination is above accepted level. 7.2. Conditions for safe storage, including any incompatibilities Store at moderate temperatures in dry,  well ventilated area. Storage Class Toxic storage. 7.3. Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters
Name STD TWA – 8 Hrs STEL – 15 Min Notes
PHOSPHORIC ACID …% WEL 1  mg/m3 2  mg/m3
PROPAN-2-OL WEL 400  ppm 999  mg/m3 500  ppm 1250  mg/m3
WEL = Workplace Exposure Limit. Ingredient Comments WEL = Workplace Exposure Limits 8.2. Exposure controls Protective equipment Engineering measures Provide adequate general and local exhaust ventilation. Respiratory equipment If ventilation is insufficient,  suitable respiratory protection must be provided.  Wear mask supplied with:  Gas cartridge suitable for organic substances. Hand protection Protective gloves must be used if there is a risk of direct contact or splash.  Use protective gloves made of:  Nitrile.  Use thin cotton gloves inside the rubber gloves if allergy risk. Eye protection Wear splash-proof eye goggles to prevent any possibility of eye contact. Hygiene measures Wash promptly if skin becomes contaminated.  Wash hands at the end of each work shift and before eating,  smoking and using the toilet. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance       Fibrous Paste Colour   Black. Odour      Solvent. Solubility              Insoluble in water Relative density                1.45 Flash point (°C) 50 CC (Closed cup). 9.2. Other information SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity 10.2. Chemical stability Stable under normal temperature conditions. 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid 10.5. Incompatible materials 10.6. Hazardous decomposition products SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects General information Known or suspected carcinogen for humans. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Dangerous for the environment: May cause long-term adverse effects in the aquatic environment. 12.1. Toxicity 12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil 12.5. Results of PBT and vPvB assessment 12.6. Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS General information This material is classified as special waste as defined by Special Waste Regulations 1996 and must be disposed of by an authorised contractor 13.1. Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION 14.1. UN number UN No. (ADR/RID/ADN)                1133 UN No. (IMDG)                 1133 UN No. (ICAO) 1133 14.2. UN proper shipping name Proper Shipping Name  ADHESIVES (NAPHTHA (PETROLEUM), HYDROSULFURIZED HEAVY; LOW BOILING) 14.3. Transport hazard class(es) ADR/RID/ADN Class        3 ADR/RID/ADN Class        Class 3: Flammable liquids. ADR Label No.             3 IMDG Class         3 ICAO Class/Division         3 Transport Labels FLAMMABLE LIQUID  3 14.4. Packing group ADR/RID/ADN Packing group      III IMDG Packing group       III ICAO Packing group   III 14.5. Environmental hazards Environmentally Hazardous Substance/Marine Pollutant 14.6. Special precautions for user EMS       F-E,  S-D Emergency Action Code                •3YE Hazard No. (ADR)  30 Tunnel Restriction Code                (D/E) 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health. Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37.

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